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Sustainable Thermoplastic Elastomers from Commercial Cyclic Esters: One-Pot Synthesis of Poly(l‑lactide)‑ b‑(δ-hexalactone- stat-ε-caprolactone)‑ b‑(l‑lactide) and Its Chemical Recycling to the Monomers

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We report the one-pot synthesis of ABA triblock copolymers composed of poly-(l-lactide) (PLA) as hard segments and δ-hexalactone/ε-caprolactone (HL/CL) copolymers as soft midblock. Use of an environmentally benign and highly active and living Fe-(II)-based c... ...