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Enantioselective Synthesis of Triarylmethanes via Palladium-Catalyzed Desymmetric Carbonylation of Cyclic Diaryliodonium Salts

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A highly enantioselective desymmetric strategy was developed for the synthesis of enantioenriched triarylmethanes via palladium-catalyzed carbonylation reactions of six-membered cyclic diaryliodonium salts with CO gas and alcohols/amines. This methodology demo... ...