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Cu-Catalyzed Atroposelective Protoboration of Allenes to Access Stereodefined Tetrasubstituted Axially Chiral Alkenylboronates

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Alkenylboronates represent a cornerstone functional group in modern organic synthesis owing to their versatile reactivity in Suzuki-Miyaura cross-coupling reactions and other key transformations. However, catalytic asymmetric methods for producing stereodefine... ...