ZnPCl7: a compositionally and structurally unprecedented metal-phospho-rus halide
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The synthesis and crystal structure of an unprecedented compound, zinc phospho-rus hepta-chloride or catena-poly[phospho-rus tetra-chloride [[di-chlor-ido-zinc]-μ-chlorido]], ZnPCl7 or {[PCl4][ZnCl3]} n , are reported. The reaction of ZnCl2 with PCl5 in a 1:1... ...
