Importance of Polar Effects in Halogen-Atom Transfer from Alkyl Iodides to α‑Aminoalkyl Radicals. A Kinetic and Computational Evaluation of the Role of Structural and Medium Effects
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α-Aminoalkyl radicals have emerged as practical halogen-atom transfer (XAT) agents, enabling the formation of carbon radicals from unactivated alkyl and aryl halides under mild conditions. A recent study correctly revised some of the XAT rate constants for th... ...
