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Rh(I)-Catalyzed Dearomative Cycloisomerization of Furan-Tethered o-Alkynylphenyl Nitrones to Tropane-Containing Polycycles

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A synthetic method for the assembly of dihydrofuran-fused tropane-containing polycycles that relies on rhodium(I)-catalyzed 6-exo-dig cycloaddition/internal redox (IR)/azomethine ylide formation/dearomative [3 + 2] cycloaddition of furan-tethered o-alkynylphen... ...