Nickel-Catalyzed Enantioselective Reductive Alkenylation of N-Pyridyl Aldimines via a Mechanism of Elementary 1,4-Addition
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Chiral nickel complexes of isoquinox catalyze an asymmetric reductive alkenylation of N-picolyl aldimines with readily available alkenyl bromides, triflates, and tosylates as carbon electrophiles. The method features neutral and mild conditions, ready scalabil... ...
