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Visible Light Promoted Alkenyl C-H Bond Addition to Dienes and Aldehydes for the Synthesis of Frameworks Relevant to Polyketide Natural Products

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Cp*Co-(III)-catalyzed sequential addition of alkenyl C-(sp2)-H bonds to dienes and aldehydes provides products with two additional C-C σ bonds with the simultaneous introduction of contiguous stereogenic centers with high selectivity. Blue LED irradiation is ... ...