Crystal structure and computational analysis of tetra-kis-(aceto-nitrile)-bis-(nona-fluoro- tert-butanolato)titanium(III) complex as a salt of the weakly coordinating [Al{OC(CF3)3}4]- anion
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The title compound, [Ti(C4F9O)2(C2H3N)4][Al(C4F9O)4] or [Ti{OC(CF3)3}2(CH3CN)4][Al{OC(CF3)3}4], is the first structurally characterized complex of TiIII containing four aceto-nitrile mol-ecules and perfluorinated alk-oxy-aluminate in its coordination sphere. T... ...
