Synthesis and structure of a tetra-hedral homoleptic CuI complex with xylyl isocyanide
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Treatment of the CuI precursor [Cu(NCMe)4]PF6 with excess (10 equivalents) of relatively bulky xylyl isocyanide formed a tetra-(isocyanide) complex, namely, tetra-kis-(2,6-di-methyl-phenylisocyanide)copper(I) hexa-fluoro-phosphate, [Cu(C9H9N)4]PF6 or [Cu(CNX-y... ...
