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Molecular communication system using Zn2+ selective supramolecular nanochannel to induce photoregulated catalysis

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We developed synthetic ionophores that self-assemble into supramolecular nanochannels for the transport of Zn2+ across lipid bilayers. The translocated Zn2+ forms a photoactive PPIX-Zn2+ complex that generates 1O2 to oxidize tryptophan, establishing a Zn2+-med... ...