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Selective CO2 hydrogenation enhanced by tuning the zinc content in nickel catalysts

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Electron-rich Ni sites in Ni3Zn-Al2O3 drive CO production through monodentate formate decomposition. Meanwhile, a Zn-evaporation-mediated strategy was proposed to tune Zn content, and engineered electron-deficient Ni-Al2O3 promotes CH4 formation by enabling bi... ...