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B(C6F5)3-Catalyzed (5 + 1)-Annulation of Enynamides with Trihydrosilanes en Route to the Synthesis of 1,4-Azasilines

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Silaazacycles are emerging as promising heavier bioisosteres of N-heterocycles in drug discovery. Among them, 1,4-azasiline, a versatile scaffold that enables access to diverse silaazacycles, has remained underexplored, largely due to the lack of efficient syn... ...