Post-Transition-State Dynamics Induced Product Diversity in the Thermal Rearrangement of Cyclopropenyl Azides
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Cyclopropenyl azides (1) are known to undergo three major thermal rearrangements, namely, 3,3-sigmatropic rearrangement to form 1,2,3-triazine (2), allylic arrangement to form the degenerate product (3), and N2 elimination to form azete (4). Previous experimen... ...