(CF3S)2C═S: Electrophilic Site at the Thiocarbonyl Sulfur for the Incorporation of Multiple CF3S Groups
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Although the thiocarbonyl group is typically attacked at sulfur due to orbital control, strong σ-electron-withdrawing groups can invert this reactivity, rendering the carbon electrophilic. Herein, we demonstrate that (CF3S)2C═S, despite bearing two strongly ... ...
