Enantioselective Beckmann Rearrangement through Organocatalytic Desymmetrization of Cyclobutanones for the Synthesis of 4,4-Disubstituted γ-Lactams
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The Beckmann rearrangement stands as a powerful and atom economic transformation, and its enantioselective version has not yet been found. This work presents the organocatalytic enantioselective desymmetric synthesis of γ-lactams from prochiral 3,3-disubstitu... ...
