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Beyond Rigid Frameworks: A Dynamic 2D Supramolecular Organic Network of Luminescent Radicals in Water

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We report the design and synthesis of a water-soluble luminescent radical, TTM-3IMB, which spontaneously assembles with cucurbit[8]uril (CB[8]) into a well-defined 2D honeycomb supramolecular organic framework (SOF) in aqueous solution. Unlike conventional cov... ...