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Synthesis of (E)-Silyl-Acrylates via Ruthenium-Catalyzed Selective Dehydrogenative Si-H/C-H Silylation of Acrylates

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An efficient and selective ruthenium-catalyzed dehydrogenative Si-H/C-H silylation of acrylates is described. A broad range of (E)-silylated acrylates could be easily synthesized with good functional group tolerance in moderate to excellent yields under mild c... ...