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Redox-Neutral Radical Annulation of Challenging Alkynes with Aryl Sulfoxonium Ylides for 1-Naphthol Synthesis

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This radical strategy represents the first use of sulfoxonium ylide-derived radicals in 1-naphthol synthesis and overcomes the substrate limitations of classical carbene-based methods. It enables annulation of unactivated terminal alkynes─previously challengi... ...