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Asymmetric Electrooxidation of Indoles: Mechanistic Insights from an Enantioselective Bromoradical Addition Pathway

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Oxidative rearrangement of tetrahydro-β-carbolines (THβCs) represents a straightforward route to the synthesis of spirooxindoles. Herein, we disclose the first bromoradical (Br•)-initiated enantioselective electrooxidative rearrangement of THβCs, leading t... ...