Synthesis and Properties of Medium-Sized cis,trans-Cycloocta-1,3-diene-Pt(II) Complexes
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cis,trans-Cycloocta-1,3-dienes (TCODs) are highly strained and elusive due to rapid 4π-electrocyclization. Here, we report the first stable isolation of cis,trans-cycloocta-1,3-dienes as Pt(II) complexes. X-ray crystallography revealed marked elongation of th... ...
