An Umpolung Strategy for Palladium-Catalyzed Dearomative Allylation toward Eight-Membered N-Heterocycles
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In this study, umpolung palladium catalysis was developed for achieving 1,2-dearomative allylation followed by intramolecular cyclization. The dearomatization involves activated N-arenes and the in situ generated nucleophilic η1-allyl-palladium species from a... ...
