Rhodium-Catalyzed O-H Insertion Reactions to (2-Diazo-1,1,3,3,3-pentafluoropropyl)phosphonate: A Convenient Route to Fluorinated β-Alkoxy Vinylphosphonates
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The rhodium(II)-catalyzed insertion of benzyl and alkyl alcohols with 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate unexpectedly afforded fluorinated β-alkoxy vinylphosphonates. The reaction proceeds under mild conditions and shows broad substrate scope. Twe... ...
