Glyoxylate Sulfonyl Hydrazone Enables a Scalable Approach to Reformatsky-Type Products from Aliphatic Alcohols via Photocatalytic HAT
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Herein, a commercially available ethyl glyoxylate sulfonyl hydrazone engages in a photocatalytic hydrogen atom transfer mechanism with aliphatic alcohols, delivering β-hydroxy ester compounds without relying on transition metal chemistry. The protocol operate... ...