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Oxidative α-Amination and Aziridination of Cyclic β-Ketoesters Using Aminobenziodoxolones

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The oxidative amination of β-ketoesters with hypervalent iodine reagents bearing transferable amino groups (aminobenziodoxolones) is described. NH2-substituted and alkylamine-derived aminobenziodoxolones enable electrophilic α-amination, whereas the use of a... ...