Chemical Oxidation of Chrysene: A Structural and Theoretical Description of a Mixed-Valent Trimeric Radical Cation
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Chemical oxidation of chrysene with GaCl3 affords a trimeric chrysene radical dication, [(C18H12)3]2+, crystallized with two Ga2Cl7 - anions, as revealed by single crystal X-ray diffraction analysis. In the crystal structure, 1D π-stacked columns of chrysene ... ...
