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Halogen Atom Transfer (XAT)-Enabled Transition-Metal-Free Radical Annulation for the Construction of Phenanthrene-Derived Polycyclic Aromatic Hydrocarbons (PAHs)

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A transition-metal-free radical annulation strategy enabled by halogen atom transfer (XAT) has been developed for the direct construction of phenanthrene-derived polycyclic aromatic hydrocarbons (PAHs) from 2-iodobiaryls and terminal alkynes. This visible-ligh... ...