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Photoredox-Mediated C-N Bond Cleavage Enables Synthesis of Tetra-Substituted Olefins via Reductive Radical-Polar Crossover

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Synthesizing all-carbon tetra-substituted olefins is challenging due to steric hindrance. Herein, we report a concise photoinduced radical aryl migration strategy for accessing these valuable structures with excellent stereoselectivity under mild conditions. T... ...