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Palladium-Catalyzed Enantioselective Intramolecular C-H Arylation of o-Chloroaroylferrocenes Enabled by a Chiral Bidentate Ferrocenyl Phosphine-Pyridine Ligand

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A palladium-catalyzed enantioselective intramolecular C-H arylation with unactivated aryl chlorides has been realized. The reaction proceeds on a range of differentially substituted o-chlorobenzoylferrocenes, thus leading to structurally diverse planar-chiral ... ...