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Synthesis of Si-Bridgehead Polycyclic Aromatic Hydrocarbons via Ru-Catalyzed Double Annulation of Secondary Silanes with Internal Alkynes

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The incorporation of silicon into the bridgehead positions of polycyclic aromatic hydrocarbons is challenging because it requires successive annulations and formation of multiple Si-C bonds. This study presents a Si-H directed double annulation method for synt... ...