Photoinduced Deoxygenative Boration of Unactivated Alcohols Involving In-Situ-Formed Alkyl Iodides
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A method for the direct two-step/one-pot conversion of unactivated 1°, 2°, and 3° alcohols into the corresponding alkylboronate esters is reported. The hydroxy group is activated in situ by reaction with the Hendrickson "POP" reagent. The rapidly formed a... ...