Stereocontrolled Synthesis of 8-Hydroxycurvularol, a Sesquiterpene with a Modified Trichothecene Skeleton
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The fungal-derived natural product curvularol (3) and its relative 8β-hydroxycurvularol (4) are a type of trichothecene with unique molecular skeletons and potential as anticancer agents. On the foundation of a known substituted cyclohexenone, 11-step stereoc... ...
