Building a Mixed Polyarene π‑Stack with Charge Disparity through Chemical Oxidation: A Structural and Theoretical Investigation
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Chemical oxidation of a perylene and coronene mixture with GaCl3 results in the formation of a unique mixed polycyclic aromatic hydrocarbon (PAH) product of the composition, [(C20H12)2(C24H12)]2+(GaCl4 -)2·(C6H6)2, as revealed by single crystal X-ray diffract... ...
