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Rhenium Chalcogenide Clusters Containing para-Substituted Phenylacetylide Ligands: Synthesis, Characterization, and Investigation of Substituent Effects on Spectroscopic and Electrochemical Properties

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Four new organometallic [Re6Se8]2+-based cluster complexes containing para-substituted phenylacetylide ligands, [Re6Se8(PEt3)5(CC-C6H4-X)]-(SbF6) where X = NO2, CO2Me, CH3, and OMe, have been synthesized and fully characterized using 1H, 13C-{1H} and 31P-{1H... ...