Activation and Functionalization of Organic Disulfides by Bis(Perfluoroalkyl) Complexes of Nickel(II)
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The [(MeCN)2Ni-(Rf)2] platform was used to study the oxidative addition of 8,8'-diquinolyl disulfide. The oxidative addition proceeds to afford [Ni-(Rf)2(SR)2] intermediates, which then eliminate Raryl-S-Rfluoroalkyl products through consecutive carbon-sulfur... ...
