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Organocatalytic Ring-Opening Polymerization of Methyl-Substituted Glycolides

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Aliphatic polyesters derived from the ring-opening polymerization (ROP) of cyclic esters offers access to sustainable, depolymerizable, and renewable materials. Herein, we report the first organocatalytic ROP of dimethyl glycolide (DMG) and tetramethyl glycoli... ...