Synthesis and Characterization of the μ6‑F Compounds [NEt4][F(Cl2)3] and [NEt4][F(Br2)3]
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The reaction of tetraethylammonium polychlorides or polybromides in propionitrile with substoichiometric amounts of diluted fluorine at low temperatures leads to the non-classical interhalogen compounds [NEt4]-[F-(X2)3] (X = Cl and Br). These compounds are the... ...