Expanding the PCET Thermochemistry of CpN3: N-H Bond Strengths of Metal-Free CpN3 Molecules and the Influence of Fe(CO)3 Coordination
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Amine rich cyclopentadienyl (CpN3) ligands are electronically distinct from classical Cp ligand architectures, as they exhibit fascinating proton-coupled electron transfer (PCET) chemistry under acidic conditions in the presence and absence of transition metal... ...