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Mechanistic Insights into the Reductive N-O Bond Cleavage of O‑Acyl Hydroxylamines: Dual Reactivity as Potent Oxidants and Nitrogen Transfer Agents

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Hydroxylamine (NH2OH), an N-O containing moiety and a pivotal intermediate in the nitrogen biogeochemical cycle, typically functions under reducing conditions, in stark contrast to its isoelectronic O-O analogue, hydrogen peroxide (H2O2). Oxygen-substituted hy... ...