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Enhancing the Dendritic Tolerance of NASICON-Based Electrolytes by Grain Boundary Engineering

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A grain boundary modification strategy relying on the liquid-sintering method is proposed for using NASICON-type ceramics Na1+xZr2SixP3-xO12 as solid-state electrolytes (SSEs) for all-solid-state batteries (ASSBs). It is found that with the addition of Na3AlF6... ...