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Synthesis and characterization of dodecylamine-capped ultrasmall metallic palladium nanoparticles (2 nm)

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Dodecylamine-coated ultrasmall palladium nanoparticles were prepared by reduction of dichlorido(1,5-cyclooctadiene)palladium(ii) with tert-butylamine borane in benzene. The synthesis yielded several tens of milligrams per batch. The nature of the metal core as... ...