Oxidative Construction of Unusual Indole-Derived Intermediates en Route to Conodusine A
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We describe several approaches to the tricyclic core of conodusine A. Synthesis of a macrocyclic alkene set the stage for 1,2-olefin difunctionalization with conodusine's pendent amine. Unanticipated reactivity of an unusually labile indole mitigated the desi... ...
