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Bifunctional Silylene-Aminoborane Enables Cooperative Activation of Unsaturated Bonds and Access to Heteroatom-Enriched Polycycle

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We report the synthesis and cooperative reactivity of a bifunctional silylene-aminoborane compound, 1-Ph-2-tBu-1H-2,1-benzazaborolyl-(amidinato)silylene (1), designed to preserve the ambiphilicity of both functional units while preventing intramolecular deacti... ...