Rapid Construction of a Tyr C6-Trp C5' Linkage: Application in the Total Synthesis of Micitide 982, a Noncanonical Cyclic Peptide
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In this study, a facile synthesis method for a highly strained Tyr C6-to-Trp C5' linkage was developed. This method enables the convergent introduction of arbitrary biaryls to peptide linkers through electrochemically assisted Ni-catalyzed cross-electrophile ... ...
