Multi-Site Organoboron Catalysts Enable Sequence-Regulated Terpolymerization of Epoxides, CO2, and β-Propiolactone via Intermolecular Chain Shuttling
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Sequence regulation in synthetic polymers is essential for tailoring material properties; however, achieving precise control in polycarbonate-polyhydroxyalkanoate (PC-PHA) terpolymers derived from epoxides, CO2, and β-lactones remains challenging. Current met... ...