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Efficient C-N Coupling via Oxidation State Inversion in Asymmetric Copper-Zinc Amorphous-Like Atomic Clusters Driving Photoelectrocatalytic Urea Synthesis

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Photoelectrochemical (PEC) coupling of CO2 and nitrate presents a sustainable strategy for urea synthesis under ambient conditions. However, the complexity of the proton-coupled electron transfer process restricts the selective formation of the key intermediat... ...