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Unlocking High-Performance Four-Electron Zinc-Iodine Batteries through Halogen Bonding Inversion and Non-Identical-Frequency Molecular Vibrations

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The activation of four-electron transfer behavior through I-/I0/I+ conversion reactions is crucial for the development of high-energy-density zinc-iodine batteries (ZIBs) but is hindered by the rapid hydrolysis of I+ in protic solvents. Theoretically, the dire... ...