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Generation of alkyl radicals via C(sp3)-C(sp3) bond cleavage of xanthene-based precursors for photocatalytic Giese-type reaction

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Novel xanthene-based alkyl radical precursors were developed and subjected to photocatalytic C(sp3)-C(sp3) bond cleavage for the efficient generation of alkyl radicals, which were subsequently reacted with various alkenes to afford the corresponding Giese-type... ...