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One-Pot Sequential Coordination-Covalent Construction of Symmetry-Broken MN2O2 Catalytic Sites in Cobalt-Polyimide Polymers for Nitrate Electroreduction

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The metal-nitrogen chelated species, MN4, have shown promise as efficient electrocatalysts for nitrate reduction, yet the symmetric arrangement of N atoms results in suboptimal adsorption affinity toward reaction substrates and intermediates. The current appro... ...