Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes
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We present a study of the ability of our recently reported well-defined crown ether-coordinated alkali metal phosphides 1AM to catalyze hydrophosphination (HP) of alkynes and alkenes. In a comparative study including reaction monitoring by 1H NMR spectroscopy,... ...
